Improved hydrogen storage properties of Ti-doped sodium alanate using titanium nanoparticles as doping agents

被引:258
作者
Bogdanovic, B [1 ]
Felderhoff, M [1 ]
Kaskel, S [1 ]
Pommerin, A [1 ]
Schlichte, K [1 ]
Schüth, F [1 ]
机构
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
关键词
D O I
10.1002/adma.200304711
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
By using nanosized doping agents, the properties of Ti-catalyzed NaAlH4 storage systems are considerably improved. Hydrogenation-dehydrogenation cyclic testing shows that with nanosized TiN dopants, storage capacities of 5 wt.-% H-2 could be achieved. Doping with nanosized Ti brought hydrogenation times close to those required for practical applications, combined with high capacity (4.5 wt.-% H-2, see Figure).
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收藏
页码:1012 / +
页数:5
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