X-ray photoelectron spectroscopic studies of interactions between poly(4-vinylpyridine) and poly(styrenesulfonate) salts

被引：47

作者：

Goh, SH ^{[1
]}

Lee, SY

Zhou, X

Tan, KL

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 119260, Singapore

[2] Natl Univ Singapore, Dept Phys, Singapore 119260, Singapore

来源：

MACROMOLECULES | 1998年 / 31卷 / 13期

关键词：

D O I：

10.1021/ma980392i

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(4-vinylpyridine) (P4VPy) was blended with the lithium or zinc salt of poly(styrenesulfonate) (PSSLi and PSSZn, respectively). P4VPy formed complexes with PSSZn but not with PSSLi in water/ethanol (2:1) solutions, indicating the presence of a strong interaction between PSSZn and P4VPy.. P4VPy is immiscible with PSSLi, as shown by the appearance of two glass transitions in each P4VPy/PSSLi blend. Fourier transform infrared spectroscopic measurements showed the development of a new pyridine ring mode in P4VPy/PSSZn complexes. X-ray photoelectron spectroscopic (XPS) studies showed the development of high-binding-energy (BE) N Is peaks in all the P4VPy/PSSZn complexes but not in the P4VPy/PSSLi blends. Interaction between P4VPy and Zn2+ is also evidenced by the development of a low-BE S 2p doublet in each complex. Therefore, XPS reveals the existence of coordination between Zn2+ and P4VPy but not between Li+ and P4VPy.

引用

页码：4260 / 4264

页数：5

共 31 条

[1] TRANSITION-METAL COORDINATION IN POLYMER BLENDS AND MODEL SYSTEMS [J].

BELFIORE, LA ;

PIRES, ATN ;

WANG, YH ;

GRAHAM, H ;

UEDA, E .

MACROMOLECULES, 1992, 25 (05) :1411-1419

[2] POLYMER-POLYMER COMPLEXATION BETWEEN POLY(MONOMETHYL ITACONATE) AND POLY(VINYLPYRIDINE)S [J].

CESTEROS, LC ;

VELADA, JL ;

KATIME, I .

POLYMER, 1995, 36 (16) :3183-3189

[3] INTERPOLYMER COMPLEXATION BETWEEN POLY(P-VINYLPHENOL) AND PYRIDINE-CONTAINING POLYMERS [J].

DAI, J ;

GOH, SH ;

LEE, SY ;

SIOW, KS .

POLYMER JOURNAL, 1994, 26 (08) :905-911

[4] STUDY OF THE COMPATIBILITY OF BLENDS OF POLYMERS AND COPOLYMERS CONTAINING STYRENE, 4-HYDROXYSTYRENE AND 4-VINYLPYRIDINE [J].

DEMEFTAHI, MV ;

FRECHET, JMJ .

POLYMER, 1988, 29 (03) :477-482

[5] Compatibilization of blends containing thermotropic liquid crystalline polymers with sulfonate ionomers [J].

Dutta, D ;

Weiss, RA ;

He, JS .

POLYMER, 1996, 37 (03) :429-435

[6] COMPLEXATION AND RATE OF POLYMERIZATION OF ACRYLIC-ACID AND METHACRYLIC-ACID IN THE PRESENCE OF POLY(4-VINYLPYRIDINE) IN DILUTE METHANOL SOLUTION [J].

FUJIMORI, K ;

TRAINOR, GT ;

COSTIGAN, MJ .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1984, 22 (10) :2479-2487

[7] INITIAL AND FINAL-STATE EFFECTS IN ESCA SPECTRA OF CADMIUM AND SILVER-OXIDES [J].

GAARENSTROOM, SW ;

WINOGRAD, N .

JOURNAL OF CHEMICAL PHYSICS, 1977, 67 (08) :3500-3506

[8] BLENDS OF POLY(MONOALKYLITACONATES) POLY(VINYLPYRIDINES) AND MODEL MOLECULES [J].

GARGALLO, L ;

GATICA, N ;

RADIC, D .

INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS, 1994, 27 (1-2) :107-115

[9] X-ray photoelectron spectroscopic studies of ionic interactions between sulfonated polystyrene and poly(styrene-co-4-vinylpyridine) [J].

Goh, SH ;

Lee, SY ;

Dai, J ;

Tan, KL .

POLYMER, 1996, 37 (23) :5305-5308

[10]

HARA M, 1984, POLYM ENG SCI, V27, P1306

← 1 2 3 4 →