X-ray photoelectron spectroscopic studies of interactions between poly(4-vinylpyridine) and poly(styrenesulfonate) salts

被引：47

作者：

Goh, SH ^{[1
]}

Lee, SY

Zhou, X

Tan, KL

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 119260, Singapore

[2] Natl Univ Singapore, Dept Phys, Singapore 119260, Singapore

来源：

MACROMOLECULES | 1998年 / 31卷 / 13期

关键词：

D O I：

10.1021/ma980392i

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(4-vinylpyridine) (P4VPy) was blended with the lithium or zinc salt of poly(styrenesulfonate) (PSSLi and PSSZn, respectively). P4VPy formed complexes with PSSZn but not with PSSLi in water/ethanol (2:1) solutions, indicating the presence of a strong interaction between PSSZn and P4VPy.. P4VPy is immiscible with PSSLi, as shown by the appearance of two glass transitions in each P4VPy/PSSLi blend. Fourier transform infrared spectroscopic measurements showed the development of a new pyridine ring mode in P4VPy/PSSZn complexes. X-ray photoelectron spectroscopic (XPS) studies showed the development of high-binding-energy (BE) N Is peaks in all the P4VPy/PSSZn complexes but not in the P4VPy/PSSLi blends. Interaction between P4VPy and Zn2+ is also evidenced by the development of a low-BE S 2p doublet in each complex. Therefore, XPS reveals the existence of coordination between Zn2+ and P4VPy but not between Li+ and P4VPy.

引用

页码：4260 / 4264

页数：5

共 31 条

[21] STRUCTURE AND SORPTION PROPERTIES OF THE POLYION COMPLEX BETWEEN POLY(ACRYLIC ACID) AND POLY(4-VINYLPYRIDINE) [J].

OYAMA, HT ;

NAKAJIMA, T .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1983, 21 (10) :2987-2995

[22] TRANSITION-METAL COORDINATION FOR COMPLEXING POLYMER BLENDS [J].

PEIFFER, DG ;

DUVDEVANI, I ;

AGARWAL, PK ;

LUNDBERG, RD .

JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS, 1986, 24 (11) :581-586

[23] MISCIBLE BLENDS OF ZINC-NEUTRALIZED SULFONATED POLYSTYRENE AND POLY(2,6-DIMETHYL 1,4-PHENYLENE OXIDE) [J].

BELL, TR .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1992, 30 (06) :569-575

[24] Interpolymer association between poly(vinylpyridines) and poly(mono-n-alkyl itaconates). Effect of the n-alkyl substituent [J].

Velada, JL ;

Cesteros, LC ;

Katime, I .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 1996, 197 (07) :2247-2259

[25] Infrared study of the interactions between poly(vinyl pyridines) and poly(mono-n-alkyl itaconates) [J].

Velada, JL ;

Cesteros, LC ;

Katime, I .

APPLIED SPECTROSCOPY, 1996, 50 (07) :893-899

[26] HIGHLY INTERACTING POLYMER BLENDS - POLY(MONOETHYL ITACONATE)/POLY(VINYLPYRIDINE)S [J].

VELADA, JL ;

CESTEROS, LC ;

MEAURIO, E ;

KATIME, I .

POLYMER, 1995, 36 (14) :2765-2772

[27]

WAGNE CD, 1975, FARADAY DISCUSS, P291

[28] X-ray photoelectron spectroscopic studies of ionic interactions in poly(styrenesulfonic acid)/poly(vinylpyridine) complexes [J].

Zhou, X ;

Goh, SH ;

Lee, SY ;

Tan, KL .

APPLIED SURFACE SCIENCE, 1998, 126 (1-2) :141-147

[29] X-ray photoelectron spectroscopic studies of interactions between poly(p-vinylphenol) and poly(vinylpyridine)s [J].

Zhou, X ;

Goh, SH ;

Lee, SY ;

Tan, KL .

APPLIED SURFACE SCIENCE, 1997, 119 (1-2) :60-66

[30] Interpolymer complexation between poly(vinylphosphonic acid) and poly(vinylpyridine)s [J].

Zhou, X ;

Goh, SH ;

Lee, SY ;

Tan, KL .

POLYMER, 1997, 38 (21) :5333-5338

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