Solvent effect on crystal polymorphism:: Why addition of methanol or ethanol to aqueous solutions induces the precipitation of the least stable β form of glycine

被引：210

作者：

Weissbuch, I ^{[1
]}

Torbeev, VY ^{[1
]}

Leiserowitz, L ^{[1
]}

Lahav, M ^{[1
]}

机构：

[1] Weizmann Inst Sci, Dept Mat & Interfaces, IL-76100 Rehovot, Israel

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 21期

关键词：

crystal growth; glycine; polymorphism; solvent effects;

D O I：

10.1002/anie.200500164

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Graph Presented) Crystallization of the thermodynamically metastable β glycine is explained on the basis of its growth at the opposite poles of the crystal (see graph) and by considering the structure of the relevant surfaces of the three polymorphs and their interactions with solvent molecules. © 2005 Wiley-VCH Verlag GmbH & Co, KGaA.

引用

页码：3226 / 3229

页数：4

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