Non-covalently solid-phase bound catalysts for organic synthesis

被引:46
作者
Horn, J [1 ]
Michalek, F [1 ]
Tzschucke, CC [1 ]
Bannwarth, W [1 ]
机构
[1] Univ Freiburg, Inst Organ Chem & Biochem, D-79104 Freiburg, Germany
来源
IMMOBILIZED CATALYSTS: SOLID PHASES, IMMOBILIZATION AND APPLICATIONS | 2004年 / 242卷
关键词
supported catalysts; non-covalent immobilization; heterogeneous catalysis;
D O I
10.1007/b96873
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Catalysts immobilized on solid supports have become valuable tools for simplified product isolation and catalyst recycling. An alternative to covalent attachment to a solid support is to immobilize catalysts by non-covalent bonding through hydrogen bridges, or ionic, hydrophobic or fluorous interactions. Compared to covalent attachment, such non-covalent approaches increase the flexibility in the choice of the support material, reaction conditions and work-up strategies. Numerous catalytic reactions employing one of these non-covalent bonding strategies have meanwhile appeared in the literature.
引用
收藏
页码:43 / 75
页数:33
相关论文
共 82 条
[1]   Palladium catalysed Heck and enantioselective allylic substitution reactions using reverse phase silica supports [J].
Anson, MS ;
Mirza, AR ;
Tonks, L ;
Williams, JMJ .
TETRAHEDRON LETTERS, 1999, 40 (39) :7147-7150
[2]   SUPPORTED AQUEOUS-PHASE CATALYSTS [J].
ARHANCET, JP ;
DAVIS, ME ;
MEROLA, JS ;
HANSON, BE .
JOURNAL OF CATALYSIS, 1990, 121 (02) :327-339
[3]   HYDROFORMYLATION BY SUPPORTED AQUEOUS-PHASE CATALYSIS - A NEW CLASS OF HETEROGENEOUS CATALYSTS [J].
ARHANCET, JP ;
DAVIS, ME ;
MEROLA, JS ;
HANSON, BE .
NATURE, 1989, 339 (6224) :454-455
[4]   Hydroformylation of linalool in a supported aqueous phase catalyst by immobilized rhodium complex:: kinetic study [J].
Benaissa, M ;
Jáuregui-Haza, UJ ;
Nikov, I ;
Wilhelm, AM ;
Delmas, H .
CATALYSIS TODAY, 2003, 79 (1-4) :419-425
[5]  
Betzemeier B, 1999, TOP CURR CHEM, V206, P61
[6]   Heck reaction using nickel/TPPTS catalyst and inorganic base on supported ethylene glycol phase [J].
Bhanage, BH ;
Zhao, FY ;
Shirai, M ;
Arai, M .
CATALYSIS LETTERS, 1998, 54 (04) :195-198
[7]   Simultaneous application of two or more supported liquid-phase organometallic catalysts: heterogeneous multifunctional reaction systems [J].
Bhanage, BM ;
Fujita, S ;
Yoshida, T ;
Sano, Y ;
Arai, M .
TETRAHEDRON LETTERS, 2003, 44 (17) :3505-3507
[8]   Heterogeneous catalyst system for Heck reaction using supported ethylene glycol phase Pd/TPPTS catalyst with inorganic base [J].
Bhanage, BM ;
Shirai, M ;
Arai, M .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 145 (1-2) :69-74
[9]   A comparison between silica-immobilized ruthenium(II) single sites and silica-supported ruthenium nanoparticles in the catalytic hydrogenation of model hetero- and polyaromatics contained in raw oil materials [J].
Bianchini, C ;
Dal Santo, V ;
Meli, A ;
Moneti, S ;
Moreno, M ;
Oberhauser, W ;
Psaro, R ;
Sordelli, L ;
Vizza, F .
JOURNAL OF CATALYSIS, 2003, 213 (01) :47-62
[10]   Preparation, characterization, and performance of tripodal polyphosphine rhodium catalysts immobilized on silica via hydrogen bonding [J].
Bianchini, C ;
Burnaby, DG ;
Evans, J ;
Frediani, P ;
Meli, A ;
Oberhauser, W ;
Psaro, R ;
Sordelli, L ;
Vizza, F .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (25) :5961-5971