A new narrow band gap electroactive polymer: Poly[2,5-bis{2-(3,4-ethylenedioxy)thienyl}silole]

被引：34

作者：

Lee, Y

Sadki, S

Tsuie, B

Reynolds, JR ^{[1
]}

机构：

[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

[2] Univ Florida, Ctr Macromol Sci & Engn, Gainesville, FL 32611 USA

[3] Sungkyunkwan Univ, Dept Chem Engn, Suwon 440746, South Korea

[4] Ecole Normale Super, Lab Photophys & Photochim Supramol & Macromol, UMR 8531, CNRS, F-94235 Cachan, France

来源：

CHEMISTRY OF MATERIALS | 2001年 / 13卷 / 07期

关键词：

D O I：

10.1021/cm010138w

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new silole-containing monomer, 1,1-dihexyl-3,4-diphenyl-2,5-bis{2-(3,4-ethylenedioxy)-thienyl}silole, was synthesized and electropolymerized at a quite low potential (E-ox,E-m = 0.29 V vs Fc/Fc(+)) to yield an electroactive polymer. Spectroelectrochemical and colorimetric analysis has shown that the polymer switches between blue and transmissive yellow-green upon doping. The low-lying LUMO levels of the siloles, combined with the electron-rich character of the 3,4-ethylene dioxythiophene units, confer upon this new polymer a narrow band gap of 1.3-1.4 eV.

引用

页码：2234 / +

页数：4

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