The chemistry and biochemistry of vanadium and the biological activities exerted by vanadium compounds

被引：1219

作者：

Crans, DC ^{[1
]}

Smee, JJ ^{[1
]}

Gaidamauskas, E ^{[1
]}

Yang, LQ ^{[1
]}

机构：

[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 02期

关键词：

D O I：

10.1021/cr020607t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The properties of vanadium and the biological activities exerted by vanadium compounds were analyzed. Vanadium compounds exhibited increasing numbers of enzyme activities. vanadate was placed by the vanadate-phosphate analogy in a central position to interact effectively with phosphorylases. The ability of V-complexes to act as peroxides, catalases, and nitrogenases was also analyzed. The reactions of V-compounds included redox proceses. But vanadate could not be a perfect transition state analogue and was not able to provide the entire binding affinity, anticipated for ideal analogue.

引用

页码：849 / 902

页数：54

共 806 条

[1] Synthesis and structural studies of early transition metalloporphyrin complexes .1. X-ray structures of meso-5,10,15,20 tetratolyl hafnium(IV) mu-dioxo dimer complex and meso-5,10,15,20 tetratolyl porphyrin vanadium(IV) oxo complex [J].

Afzal, D ;

Baughman, R ;

James, A ;

Westmeyer, M .

SUPRAMOLECULAR CHEMISTRY, 1996, 6 (3-4) :395-399

[2] Oxidative deamination by hydrogen peroxide in the presence of metals [J].

Akagawa, M ;

Suyama, K .

FREE RADICAL RESEARCH, 2002, 36 (01) :13-21

[3]

ALBER T, 1983, CIBA F SYMP, V93, P4

[4] PHOSPHATE COMPLEXATION OF OXOVANADIUM(IV) - EVIDENCE OF BIDENTATE CHELATION OF ORTHOPHOSPHATE [J].

ALBERICO, E ;

MICERA, G .

INORGANICA CHIMICA ACTA, 1994, 215 (1-2) :225-227

[5] CHARACTERIZATION OF IRON UPTAKE FROM FERRIOXAMINE-B BY CHLORELLA-VULGARIS [J].

ALLNUTT, FCT ;

BONNER, WD .

PLANT PHYSIOLOGY, 1987, 85 (03) :746-750

[6] N-HYDROXY-ALPHA,ALPHA'-IMINODIPROPIONIC AND N-HYDROXYIMINODIACETIC ACID AS COMPLEXING AGENTS AND AN EXAMPLE FOR SELECTIVE COORDINATION OF THE VANADYL ION VO2+ IN AMAVADINE [J].

ANDEREGG, G ;

KOCH, E ;

BAYER, E .

INORGANICA CHIMICA ACTA, 1987, 127 (02) :183-188

[7] UPTAKE OF VANADIUM BY THE ASCIDIAN ASCIDIA-CERATODES [J].

ANDERSON, DH ;

BERG, JR ;

SWINEHART, JH .

COMPARATIVE BIOCHEMISTRY AND PHYSIOLOGY A-PHYSIOLOGY, 1991, 99 (1-2) :151-158

[8] THE DISTRIBUTION OF VANADIUM AND SULFUR IN THE BLOOD-CELLS, AND THE NATURE OF VANADIUM IN THE BLOOD-CELLS AND PLASMA OF THE ASCIDIAN, ASCIDIA-CERATODES [J].

ANDERSON, DH ;

SWINEHART, JH .

COMPARATIVE BIOCHEMISTRY AND PHYSIOLOGY A-PHYSIOLOGY, 1991, 99 (04) :585-592

[9] Elevated intakes of supplemental chromium improve glucose and insulin variables in individuals with type 2 diabetes [J].

Anderson, RA ;

Cheng, NZ ;

Bryden, NA ;

Polansky, MM ;

Cheng, NP ;

Chi, JM ;

Feng, JG .

DIABETES, 1997, 46 (11) :1786-1791

[10] Asymmetric sulfoxidation catalyzed by a vanadium-containing bromoperoxidase [J].

Andersson, M ;

Willetts, A ;

Allenmark, S .

JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (24) :8455-8458

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