The chemistry and biochemistry of vanadium and the biological activities exerted by vanadium compounds

被引：1219

作者：

Crans, DC ^{[1
]}

Smee, JJ ^{[1
]}

Gaidamauskas, E ^{[1
]}

Yang, LQ ^{[1
]}

机构：

[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 02期

关键词：

D O I：

10.1021/cr020607t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The properties of vanadium and the biological activities exerted by vanadium compounds were analyzed. Vanadium compounds exhibited increasing numbers of enzyme activities. vanadate was placed by the vanadate-phosphate analogy in a central position to interact effectively with phosphorylases. The ability of V-complexes to act as peroxides, catalases, and nitrogenases was also analyzed. The reactions of V-compounds included redox proceses. But vanadate could not be a perfect transition state analogue and was not able to provide the entire binding affinity, anticipated for ideal analogue.

引用

页码：849 / 902

页数：54

共 806 条

[61] THE ACID PROMOTED DISPROPORTIONATION OF A VANADIUM(IV) PHENOLATE - IMPLICATIONS FOR VANADIUM UPTAKE IN TUNICATES [J].

BONADIES, JA ;

PECORARO, VL ;

CARRANO, CJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (15) :1218-1219

[62] Mechanistic implications for Escherichia coli cofactor-dependent phosphoglycerate mutase based on the high-resolution crystal structure of a vanadate complex [J].

Bond, CS ;

White, MF ;

Hunter, WN .

JOURNAL OF MOLECULAR BIOLOGY, 2002, 316 (05) :1071-1081

[63] SPECTROSCOPIC AND MAGNETOSTRUCTURAL CORRELATIONS IN OXE-BRIDGED DINUCLEAR VANADIUM(III) COMPLEXES OF POTENTIAL BIOLOGICAL SIGNIFICANCE [J].

BOND, MR ;

CZERNUSZEWICZ, RS ;

DAVE, BC ;

YAN, Q ;

MOHAN, M ;

VERASTEGUE, R ;

CARRANO, CJ .

INORGANIC CHEMISTRY, 1995, 34 (23) :5857-5869

[64]

Bontchev RP, 1999, ANGEW CHEM INT EDIT, V38, P1937, DOI 10.1002/(SICI)1521-3773(19990712)38:13/14<1937::AID-ANIE1937>3.0.CO

[65]

2-5

[66]

BONTCHEV RP, 1999, INORG CHEM, P38

[67] NUCLEAR MAGNETIC-RESONANCE AND NEUTRON-DIFFRACTION STUDIES OF THE COMPLEX OF RIBONUCLEASE-A WITH URIDINE VANADATE, A TRANSITION-STATE ANALOG [J].

BORAH, B ;

CHEN, CW ;

EGAN, W ;

MILLER, M ;

WLODAWER, A ;

COHEN, JS .

BIOCHEMISTRY, 1985, 24 (08) :2058-2067

[68]

Bortolini O, 2003, EUR J INORG CHEM, P42

[69]

Bortolini O, 1999, EUR J INORG CHEM, P1489

[70] ULTRASTRUCTURAL LOCALIZATION OF VANADIUM IN THE BLOOD-CELLS OF ASCIDIACEA [J].

BOTTE, L ;

SCIPPA, S ;

VINCENTIIS, MD .

EXPERIENTIA, 1979, 35 (09) :1228-1230

← 2 3 4 5 6 7 8 9 10 11 →