Formation and growth of spinel-type LiMn2O4 single crystals by LiCl-MnCl2 flux evaporation

被引：9

作者：

Tang, WP

Yang, XJ

Kanoh, H

Ooi, K

机构：

[1] Res Inst Solvothermal Technol, Takamatsu, Kagawa 7610301, Japan

[2] Natl Inst Adv Ind Sci & Technol, Marine Resources & Environm Res Inst, Takamatsu, Kagawa 7610395, Japan

来源：

CHEMISTRY LETTERS | 2001年 / 06期

关键词：

D O I：

10.1246/cl.2001.524

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Octahedral and rectangle-like LiMn2O4 single crystals larger than 0.1 x 0.1 x 0.1 mm(3) in size were synthesized by evaporating a melt of LiCl and MnCl2 at 750 degreesC. The nucleation and growth of the crystals proceeds on the wall of a pure alumina crucible. Phase analysis showed that purity of phase was affected by MnCl2 partial pressure.

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页码：524 / 525

页数：2

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