Poly(methimazolyl)borate complexes of platinum

被引：47

作者：

Crossley, IR ^{[1
]}

Hill, AF ^{[1
]}

Willis, AC ^{[1
]}

机构：

[1] Australian Natl Univ, Inst Adv Studies, Res Sch Chem, Canberra, ACT, Australia

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 21期

关键词：

D O I：

10.1021/om050377j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of iodotrimethylplatinum(l-V) with 1 equiv of Na[HB(mt)(3)] or Na[H2B(mt)(2)] (mt = methimazolyl) affords respectively the octahedral organometallic complexes [PtMe3{HB(mt)(3)}] and [PtMe3-{H2B(mt)(2)}], the first isolated examples of poly(methimazolyl)borate complexes of platinum, which prove remarkably stable toward the reductive elimination of methane. The latter reacts further with [PtMe3I](4) to afford the novel, sulfur-bridged dinuclear complex [Me-3-Pt{mu-H2B(mt)(2)}PtMe3I].

引用

页码：4889 / 4892

页数：4

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