The first rhodaboratrane:: [RhCl(PPh3){B(mt)3}](Rh→B) (mt = methimazolyl)

被引:103
作者
Crossley, IR
Foreman, MRS
Hill, AF [1 ]
White, AJP
Williams, DJ
机构
[1] Australian Natl Univ, Inst Adv Studies, Res Sch Chem, Canberra, ACT, Australia
[2] Univ London Imperial Coll Sci Technol & Med, London SW7 2AY, England
关键词
D O I
10.1039/b413305f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of [Rh(C6H5)Cl-2(PPh3)(2)] with Na[HB(mt)(3)] (mt = methimazolyl) provides [RhCl(PPh3){B(mt)(3)}](Rh-->B) the first authentic example of a compound with a rhodium boron dative bond.
引用
收藏
页码:221 / 223
页数:3
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