Polyazolyl chelate chemistry. 12. An unusual mode of coordination for the hydrotris(methimazolyl)borato ligand

被引：112

作者：

Foreman, MRSJ ^{[1
]}

Hill, AF

Owen, GR

White, AJP

Williams, DJ

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

[2] Australian Natl Univ, Res Sch Chem, Inst Adv Studies, Canberra, ACT, Australia

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 22期

关键词：

D O I：

10.1021/om030550g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of [RuHCl(CO)(PPh3)(3)] or [RuH(NCMe)(2)(CO)(PPh3)(2)] ClO4 with Na[HB(mt)(3)] (mt = methimazolyl) provide the structurally characterized complex [RuH(CO)(PPh3){kappa(3)-H,S,S"-HB(mt)(3)}], which hydrogenates ethynylbenzene to styrene with formation of the ruthenaboratrane [Ru(CO)(PPh3){B(mt)(3)}](Ru-->B).

引用

页码：4446 / 4450

页数：5

共 44 条

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