Electrochemical performance of an all-solid-state lithium ion battery with garnet-type oxide electrolyte

被引：313

作者：

Ohta, Shingo ^{[1
]}

Kobayashi, Tetsuro ^{[1
]}

Seki, Juntaro ^{[1
]}

Asaoka, Takahiko ^{[1
]}

机构：

[1] Toyota Cent Res & Dev Labs Inc, Nagakute, Aichi 4801192, Japan

来源：

JOURNAL OF POWER SOURCES | 2012年 / 202卷

关键词：

All-solid-state lithium ion battery; Solid electrolyte; Oxide ceramics; Electrochemical property; INTERFACE; LICOO2; LI7LA3ZR2O12; GRAPHITE;

D O I：

10.1016/j.jpowsour.2011.10.064

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electrochemical performance and charge transfer resistance of an all-solid-state lithium ion battery consisting of LiCoO2 (LCO; cathode), Li6.75La3Zr1.75Nb0.25O12 (LLZONb; solid electrolyte), and lithium (anode) were investigated. This battery has favorable charge-discharge behavior and exhibits good stable cycle performance. No other reaction phase or exfoliation was evident at the interface between LCO and LLZONb after 100 charge-discharge cycles. The interfacial resistance between LCO and LLZONb is comparable to that of lithium ion batteries with liquid organic electrolytes, and the activation energy of the interfacial resistance of this battery is still lower than that of a lithium ion battery with a liquid organic electrolyte. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：332 / 335

页数：4

共 17 条

[1] Lithium-ion transfer at the interface between lithium-ion conductive ceramic electrolyte and liquid electrolyte - A key to enhancing the rate capability of lithium-ion batteries [J].

Abe, T ;

Sagane, F ;

Ohtsuka, M ;

Iriyama, Y ;

Ogumi, Z .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (11) :A2151-A2154

[2] Solvated Li-ion transfer at interface between graphite and electrolyte [J].

Abe, T ;

Fukuda, H ;

Iriyama, Y ;

Ogumi, Z .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (08) :A1120-A1123

[3] STRUCTURE AND ELECTROCHEMISTRY OF LITHIUM COBALT OXIDE SYNTHESIZED AT 400-DEGREES-C [J].

GUMMOW, RJ ;

THACKERAY, MM ;

DAVID, WIF ;

HULL, S .

MATERIALS RESEARCH BULLETIN, 1992, 27 (03) :327-337

[4] Vibrational spectroscopic and electrochemical studies of the low and high temperature phases of LiCo(1-x)M(x)O(2) (M=Ni or Ti) [J].

Huang, WW ;

Frech, R .

SOLID STATE IONICS, 1996, 86-8 :395-400

[5] Charge transfer reaction at the lithium phosphorus oxynitride glass electrolyte/lithium cobalt oxide thin film interface [J].

Iriyama, Y ;

Kako, T ;

Yada, C ;

Abe, T ;

Ogumi, Z .

SOLID STATE IONICS, 2005, 176 (31-34) :2371-2376

[6] Characterization of the interface between LiCoO2 and Li7La3Zr2O12 in an all-solid-state rechargeable lithium battery [J].

Kim, Ki Hyun ;

Iriyama, Yasutoshi ;

Yamamoto, Kazuo ;

Kumazaki, Shota ;

Asaka, Toru ;

Tanabe, Kinuka ;

Fisher, Craig A. J. ;

Hirayama, Tsukasa ;

Murugan, Ramaswamy ;

Ogumi, Zempachi .

JOURNAL OF POWER SOURCES, 2011, 196 (02) :764-767

[7] Lithium ion phase-transfer reaction at the interface between the lithium manganese oxide electrode and the nonaqueous electrolyte [J].

Kobayashi, S ;

Uchimoto, Y .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (27) :13322-13326

[8] Compatibility of Li7La3Zr2O12 Solid Electrolyte to All-Solid-State Battery Using Li Metal Anode [J].

Kotobuki, Masashi ;

Munakata, Hirokazu ;

Kanamura, Kiyoshi ;

Sato, Yosuke ;

Yoshida, Toshihiro .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (10) :A1076-A1079

[9] Fast lithium ion conduction in garnet-type Li7La3Zr2O12 [J].

Murugan, Ramaswamy ;

Thangadurai, Venkataraman ;

Weppner, Werner .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (41) :7778-7781

[10] Lithium-ion transfer at interface between carbonaceous thin film electrode/electrolyte [J].

Ogumi, Z ;

Abe, T ;

Fukutsuka, T ;

Yamate, S ;

Iriyama, Y .

JOURNAL OF POWER SOURCES, 2004, 127 (1-2) :72-75

← 1 2 →