Syntheses and structures of organically templated iron phosphates

被引:217
作者
Lii, KH [1 ]
Huang, YF
Zima, V
Huang, CY
Lin, HM
Jiang, YC
Liao, FL
Wang, SL
机构
[1] Acad Sinica, Inst Chem, Taipei, Taiwan
[2] Natl Tsing Hua Univ, Dept Chem, Hsinchu, Taiwan
关键词
D O I
10.1021/cm980152h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Iron phosphates are of interest because of rich crystal chemistry and practical applications. New crystalline iron phosphates have been prepared in aqueous or predominantly nonaqueous solvents under mild hydrothermal conditions using organic amines as structure-directing agents. The effects of pH, solvent, and temperature on the reaction products are discussed. FePOs have been prepared with 1-D chain, 2-D layered, and 3-D open framework structures. An FePO containing a chiral amine is also synthesized. This review will summarize some of the results of the work in the area of organically templated iron phosphates.
引用
收藏
页码:2599 / 2609
页数:11
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