A binuclear copper(II) complex containing the pyrazine-2,5-dicarboxylate ligand:: Study of the magnetic exchange through the pyrazine bridge

被引：25

作者：

Beobide, G

Castillo, O

García-Couceiro, U

García-Terán, JP

Luque, A

Martínez-Ripoll, M

Román, P

机构：

[1] Univ Basque Country, Dept Quim Inorgan, E-48080 Bilbao, Spain

[2] CSIC, Inst Fis & Quim, Grp Cristalog Mol & Biol Estruct, E-28006 Madrid, Spain

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 13期

关键词：

copper; density functional calculations; magnetic properties; N ligands; pyrazine;

D O I：

10.1002/ejic.200500119

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compound [Cu-2(mu-pzdc)(phen)4](NO3)(2)(.)10H(2)O (1; pzdc = pyrazine-2,5-dicarboxylato; phen = 1,10-phenanthroline) has been structurally and magnetically characterised. Theoretical calculations have allowed us to establish a plausible magneto-structural correlation for pyrazine-bridged complexes.

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收藏

页码：2586 / 2589

页数：4

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