Cation-Exchange Porosity Tuning in Anionic Metal-Organic Frameworks for the Selective Separation of Gases and Vapors and for Catalysis

被引：157

作者：

Quartapelle Procopio, Elsa ^{[1
]}

Linares, Fatima ^{[1
]}

Montoro, Carmen ^{[1
]}

Colombo, Valentina ^{[2
]}

Maspero, Angelo ^{[2
]}

Barea, Elisa ^{[1
]}

Navarro, Jorge A. R. ^{[1
]}

机构：

[1] Univ Granada, Dept Quim Inorgan, E-18071 Granada, Spain

[2] Univ Insubria, Dipartimento Sci Chim & Ambientali, I-22100 Como, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 40期

关键词：

gas separation; heterogeneous catalysis; ion exchange; microporous materials; porous coordination polymers; ADSORPTION;

D O I：

10.1002/anie.201003314

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Temperature matters! The separation efficiency of complex mixtures of gases (acetylene, carbon dioxide, methane, nitrogen) and vapors (benzene, cyclohex-ane) by adsorption on A[Cu3(μ3-OH) (μ3-4-carboxypyrazolato)3] (A@1) metal-organic frameworks depends on temperature and the extraframework cation A (see picture). NH4@1 also behaves as an oxidation catalyst. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7308 / 7311

页数：4