Aqueous RAFT polymerization of acrylamide and N,N-dimethylacrylamide at room temperature

被引：98

作者：

Convertine, AJ

Lokitz, BS

Lowe, AB

Scales, CW

Myrick, LJ

McCormick, CL

机构：

[1] Univ So Mississippi, Dept Polymer Sci, Hattiesburg, MS 39406 USA

[2] Univ So Mississippi, Dept Chem & Biochem, Hattiesburg, MS 39406 USA

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2005年 / 26卷 / 10期

关键词：

block copolymers; gel permeation chromatography (GPC); hydrophilic polymers; kinetics (polymerization); RAFT;

D O I：

10.1002/marc.200500042

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The first example of a room temperature reversible addition fragmentation chain transfer polymerization conducted directly in aqueous media is detailed. Under these conditions acrylamide and N,N-dimethylacrylamide may be polymerized in a controlled fashion to near quantitative conversions employing a difunctional trithio-carbonate chain transfer agent (CTA). Hydrolysis studies conducted at pH 5.5 suggest that the CTA is stable up to approximately 50 degrees C.

引用

页码：791 / 795

页数：5

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