Structures of (C5H5N)(3)Al(N-3)(3), [Me(2)N(CH2)(3)]Al-2(N-3) and Me(2)(N-3)Al(H(2)NBu(t)). Low-temperature OMVPE of AlN in the absence of ammonia

被引:24
作者
Fischer, RA
Miehr, A
Sussek, H
Pritzkow, H
Herdtweck, E
Muller, J
Ambacher, O
Metzger, T
机构
[1] TECH UNIV MUNICH,INST ANORGAN CHEM,D-85747 GARCHING,GERMANY
[2] RHEIN WESTFAL TH AACHEN,INST ANORGAN CHEM,D-52056 AACHEN,GERMANY
[3] TECH UNIV MUNICH,WALTER SCHOTTKY INST,D-85748 GARCHING,GERMANY
[4] TECH UNIV MUNICH,LEHRSTUHL ANGEW MINERAL & GEOCHEM,D-85747 GARCHING,GERMANY
关键词
D O I
10.1039/cc9960002685
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
New Lewis-base stabilized monomeric azido alanes are synthesized by salt metathesis from the corresponding chloro alanes and an excess of sodium azide; thin films of crystalline AlN are grown by OMVPE at 400-850 degrees C in vacuo.
引用
收藏
页码:2685 / 2686
页数:2
相关论文
共 14 条
[1]   HIGH-RESOLUTION METAL-NMR SPECTROSCOPY OF ORGANOMETALLIC COMPOUNDS [J].
BENN, R ;
RUFINSKA, A .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (10) :861-881
[2]  
CARMALT CJ, 1996, J CHEM SOC CHEM COMM, P1453
[3]   Low-temperature OMCVD of InN thin films from the novel air-stable single-molecule precursor azido{bis[(3-dimethylamino)propyl]}indium, (N-3)In[(CH2)(3)NMe(2)](2) [J].
Fischer, RA ;
Miehr, A ;
Metzger, T ;
Born, E ;
Ambacher, O ;
Angerer, H ;
Dimitrov, R .
CHEMISTRY OF MATERIALS, 1996, 8 (07) :1356-&
[4]  
FISCHER RA, 1996, CHEM-EUR J, V2, P101
[5]   LEWIS ACIDITY OF ALANES . INTERACTIONS OF TRIMETHYLALANE WITH AMINES ETHERS AND PHOSPHINES [J].
HENRICKS.CH ;
DUFFY, D ;
EYMAN, DP .
INORGANIC CHEMISTRY, 1968, 7 (06) :1047-&
[6]   LARGE EFFECTS OF MEDIUM ON GEOMETRIES - AN AB-INITIO STUDY [J].
JIAO, HJ ;
SCHLEYER, PV .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (16) :7429-7430
[7]   The first monomeric, volatile bis-azide single-source precursor to gallium nitride thin films [J].
Miehr, A ;
Ambacher, O ;
Rieger, W ;
Metzger, T ;
Born, E ;
Fischer, RA .
CHEMICAL VAPOR DEPOSITION, 1996, 2 (02) :51-55
[8]   Lewis base adduct stabilized organogallium azides: Synthesis and dynamic NMR spectroscopic studies of novel precursors to gallium nitride and role of ammonia as reactive carrier gas [J].
Miehr, A ;
Mattner, MR ;
Fischer, RA .
ORGANOMETALLICS, 1996, 15 (08) :2053-2059
[9]  
MIEHR A, 1996, THESIS TU MUNCHEN
[10]   Aminodimethylalane (Me(2)AlNH(2)): Matrix isolation and ab initio calculations [J].
Muller, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (27) :6370-6376