Intercalation of Mg-Al layered double hydroxide by anionic surfactants:: Preparation and characterization

被引:321
作者
Costa, Francis Reny [1 ]
Leuteritz, Andreas [1 ]
Wagenknecht, Udo [1 ]
Jehnichen, Dieter [1 ]
Haeussler, Liane [1 ]
Heinrich, Gert [1 ]
机构
[1] Leibniz Inst Polymerforsch Dresden eV, D-01069 Dresden, Germany
关键词
layered double hydroxide; intercalation compounds;
D O I
10.1016/j.clay.2007.03.006
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The preparation and the characterization of intercalation compounds of Mg-Al layered double hydroxide (Mg-Al LDH) and various organic surfactants have been studied in detail. The preparation has been carried out following regeneration method. The aim of such organic modification is to prepare LDHs suitable for application in polymer-LDH nanocomposites. The LDH-surfactant hybrids have been characterized by wide angle X-ray scattering (WAXS) and Fourier transform infrared (FTIR) spectroscopy. The modified Mg-Al LDH materials show an increase in interlayer distance as compared to the unmodified Mg-Al LDH depending on the length of the surfactant anions. Thermal decomposition changed significantly after organic modification. The particle morphology was investigated by scanning electron microscopy (SEM). (C) 2007 Published by Elsevier B.V.
引用
收藏
页码:153 / 164
页数:12
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