Valorisation of corncob residues to functionalised porous carbonaceous materials for the simultaneous esterification/transesterification of waste oils

被引：60

作者：

Arneil Arancon, Rick ^{[1
]}

Barros, Higinio R., Jr. ^{[1
]}

Balu, Alina M. ^{[2
]}

Vargas, Carolina ^{[3
]}

Luque, Rafael ^{[2
]}

机构：

[1] Xavier Univ, Ateneo De Cagayan, Philippines

[2] Univ Cordoba, Dept Quim Organ, E-14014 Cordoba, Spain

[3] Univ Rey Juan Carlos, Dept Tecnol Ambiental, Madrid, Spain

来源：

GREEN CHEMISTRY | 2011年 / 13卷 / 11期

关键词：

BIODIESEL PRODUCTION; EFFICIENT PRODUCTION; SUGAR CATALYST; BIOMASS; DERIVATIVES; SHELL; ACID;

D O I：

10.1039/c1gc15908a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Functionalised porous carbonaceous materials prepared from the controlled pyrolysis of corncobs were found to provide excellent activities in the simultaneous esterification/transesterification of highly acidic waste oils to biodiesel-like mixtures. Materials carbonised at 600 degrees C (mostly microporous) containing -SO3(H) groups (ca. 1 wt% S, 0.16 mmol g(-1) -SO(3)H) exhibited the optimum yields (> 95%) to fatty acid methyl esters after 6 h of reaction.

引用

页码：3162 / 3167

页数：6

共 27 条

[1] ULTRAVIOLET AND INFRARED-ABSORPTION SPECTRA OF 2-THIOPHENESULFONAMIDES
ARCORIA, A
MACCARONE, E
MUSUMARRA, G
TOMASELLI, GA
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1974, A 30 (03) : 611 - 618
[2] Managing municipal solid waste - Energetic and environmental comparison among different management options
Beccali, G
Cellura, M
Mistretta, M
[J]. INTERNATIONAL JOURNAL OF LIFE CYCLE ASSESSMENT, 2001, 6 (04) : 243 - 249
[3] Biodiesel production via transesterification of palm olein using waste mud crab (Scylla serrata) shell as a heterogeneous catalyst
Boey, Peng-Lim
Maniam, Gaanty Pragas
Abd Hamid, Shafida
[J]. BIORESOURCE TECHNOLOGY, 2009, 100 (24) : 6362 - 6368
[4] Synthesis of acidic Al-MCM-48:: Influence of the Si/Al ratio, degree of the surfactant hydroxyl exchange, and post-treatment in NH4F solution
Campelo, JM
Luna, D
Luque, R
Marinas, JM
Romero, AA
Calvino, JJ
Rodríguez-Luque, MP
[J]. JOURNAL OF CATALYSIS, 2005, 230 (02) : 327 - 338
[5] Biomass waste-derived microporous carbons with controlled texture and enhanced hydrogen uptake
Cheng, Fangyi
Liang, Jing
Zhao, Jianzhi
Tao, Zhanliang
Chen, Jun
[J]. CHEMISTRY OF MATERIALS, 2008, 20 (05) : 1889 - 1895
[6] Hydrothermal synthesis of imidazole functionalized carbon spheres and their application in catalysis
Demir-Cakan, Rezan
Makowski, Philippe
Antonietti, Markus
Goettmann, Frederic
Titirici, Maria-Magdalena
[J]. CATALYSIS TODAY, 2010, 150 (1-2) : 115 - 118
[7] Carboxylate-Rich Carbonaceous Materials via One-Step Hydrothermal Carbonization of Glucose in the Presence of Acrylic Acid
Demir-Cakan, Rezan
Baccile, Niki
Antonietti, Markus
Titirici, Maria-Magdalena
[J]. CHEMISTRY OF MATERIALS, 2009, 21 (03) : 484 - 490
[8] Biorefineries: Current activities and future developments
Demirbas, Ayhan
[J]. ENERGY CONVERSION AND MANAGEMENT, 2009, 50 (11) : 2782 - 2801
[9] The chemical value of wheat straw combustion residues
Dodson, Jennifer R.
Hunt, Andrew J.
Budarin, Vitaly L.
Matharu, Avtar S.
Clark, James H.
[J]. RSC ADVANCES, 2011, 1 (03): : 523 - 530
[10] DONNELLY BJ, 1973, CEREAL CHEM, V50, P548

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