Calix[4]arene-based receptors with hydrogen-bonding groups immersed into a large cavity

被引：25

作者：

Pinkhassik, E ^{[1
]}

Sidorov, V ^{[1
]}

Stibor, I ^{[1
]}

机构：

[1] Inst Chem Technol, Dept Organ Chem, CR-16628 Prague, Czech Republic

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1998年 / 63卷 / 26期

关键词：

D O I：

10.1021/jo9804543

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A one-pot procedure, which combines the Ritter and Friedel-Crafts reactions, produced the first members of a new type of calix[4]arene-based receptors. The cavity in these receptors is formed by a calix[4]arene framework fixed in the cone conformation and bulky adamantyl or (and) phenylacetylene moieties. Amido and amino groups were used as potential hygrogen bond donors. Preliminary studies revealed interesting complexation properties, in particular, the tetrahedral recognition of water molecules performed by one of the receptors.

引用

页码：9644 / 9651

页数：8

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