Cleavage of the etheric bond in cyclopentadienyliron phenolphthalein complexes

被引：3

作者：

Abd-El-Aziz, AS ^{[1
]}

Bernardin, SA ^{[1
]}

Tran, K ^{[1
]}

机构：

[1] Univ Winnipeg, Dept Chem, Winnipeg, MB R3B 2E9, Canada

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 10期

关键词：

D O I：

10.1016/S0040-4039(99)00081-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of aliphatic primary amines with phenolphthalein-containing dicyclopentadienyliron complexes led to etheric bond cleavage. This unique cleavage reaction is due to nucleophilic attack by the amines ipso to the etheric group of the complexed arene, which is activated by coordination to the cationic cyclopentadienyliron moiety. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：1835 / 1838

页数：4

共 8 条

[1] A NEW CLASS OF DIIRON ARENE COMPLEXES WITH DISULFIDE AND DIAMINE BRIDGES [J].

ABDELAZIZ, AS ;

EPP, KM ;

DEDENUS, CR ;

FISHERMITH, G .

ORGANOMETALLICS, 1994, 13 (06) :2299-2308

[2] CONTROLLED DESIGN OF OLIGOMERIC ETHERS WITH PENDANT CYCLOPENTADIENYLIRON MOIETIES [J].

ABDELAZIZ, AS ;

DEDENUS, CR ;

ZAWOROTKO, MJ ;

MACGILLIVRAY, LR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (20) :3375-3393

[3] BIS(CYCLOPENTADIENYLIRON)ARENE COMPLEXES - A NEW ROUTE TO THE SYNTHESIS AND FUNCTIONALIZATION OF POLYAROMATIC ETHERS [J].

ABDELAZIZ, AS ;

SCHRIEMER, DC ;

DEDENUS, CR .

ORGANOMETALLICS, 1994, 13 (01) :374-384

[4]

ASTRUC D, 1992, NEW J CHEM, V16, P305

[5] HYDRODEAMINATION OF N,N-DIMETHYLAMINOARENETRICARBONYLCHROMIUM COMPLEXES VIA CINE AND TELE-META NUCLEOPHILIC AROMATIC SUBSTITUTIONS [J].

DJUKIC, JP ;

ROSEMUNCH, F ;

ROSE, E .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (22) :1634-1635

[6] STUDIES ON NUCLEOPHILIC-SUBSTITUTION REACTIONS WITH ETA-6-ORTHO-DICHLOROBENZENE-ETA-5-CYCLOPENTADIENYLIRON HEXAFLUOROPHOSPHATE [J].

LEE, CC ;

ABDELAZIZ, AS ;

CHOWDHURY, RL ;

GILL, US ;

PIORKO, A ;

SUTHERLAND, RG .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 315 (01) :79-92

[7] HYDRO-DE-ALKOXYLATION OF ALKOXYBENZENETRICARBONYLCHROMIUM COMPLEXES [J].

ROSEMUNCH, F ;

DJUKIC, JP ;

ROSE, E .

TETRAHEDRON LETTERS, 1990, 31 (18) :2589-2590

[8] ZWITTERIONIC SPECIES FROM DEPROTONATION OF ETA-6-ARENE-ETA-5-CYCLOPENTADIENYLIRON CATIONS AND THEIR REACTIONS AS NUCLEOPHILES [J].

SUTHERLAND, RG ;

STEELE, BR ;

DEMCHUK, KJ ;

LEE, CC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 181 (02) :411-424

← 1 →