Commensurate Adsorption of Hydrocarbons and Alcohols in Microporous Metal Organic Frameworks

被引：974

作者：

Wu, Haohan ^{[1
]}

Gong, Qihan ^{[1
]}

Olson, David H. ^{[1
]}

Li, Jing ^{[1
]}

机构：

[1] Rutgers State Univ, Dept Chem & Chem Biol, Piscataway, NJ 08854 USA

来源：

CHEMICAL REVIEWS | 2012年 / 112卷 / 02期

关键词：

BIAS MONTE-CARLO; ZEOLITIC IMIDAZOLATE FRAMEWORKS; MOLECULAR-DYNAMICS SIMULATIONS; SELECTIVE GAS-ADSORPTION; SHORT LINEAR ALKANES; DIFFERENCE-FOURIER TECHNIQUES; MAXWELL-STEFAN DIFFUSIVITY; POWDER PROFILE REFINEMENTS; LIQUID-PHASE ADSORPTION; INCOMMENSURATE TRANSITION;

D O I：

10.1021/cr200216x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Commensurate adsorption of hydrocarbons and alcohols in microporous metal-organic frameworks (MOF) is studied. Diffusion studies of hydrocarbons in microporous MOF materials represent a new topic in adsorption related research. Transport properties of guest molecules are investigated by measuring their transport diffusivity and surface permeability employing state-of-the-art and high temporal and spatial resolution IR microimaging and interference (IF) microscopy. The normal C2-C4 alcohols is found to exhibit commensurate adsorption in RPM3-Zn near room temperature. RPM4-Zn takes up a significantly less amount of benzene and o-xylene compared to RPM3-Zn. Adsorption of styrene in MIL-47 represents another very interesting case. With a CdC double bond in place of a C double bond C single bond in EB, styrene is longer and more rigid than EB.

引用

页码：836 / 868

页数：33

共 348 条

[1] Selective Adsorption and Separation of ortho-Substituted Alkylaromatics with the Microporous Aluminum Terephthalate MIL-53 [J].

Alaerts, Luc ;

Maes, Michael ;

Giebeler, Lars ;

Jacobs, Pierre A. ;

Martens, Johan A. ;

Denayer, Joeri F. M. ;

Kirschhock, Christine E. A. ;

De Vos, Dirk E. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (43) :14170-14178

[2] Selective adsorption and separation of xylene isomers and ethylbenzene with the microporous vanadium(IV) terephthalate MIL-47 [J].

Alaerts, Luc ;

Kirschhock, Christine E. A. ;

Maes, Michael ;

van der Veen, Monique A. ;

Finsy, Vincent ;

Depla, Anouschka ;

Martens, Johan A. ;

Baron, Gino V. ;

Jacobs, Pierre A. ;

Denayer, Joeri E. M. ;

De Vos, Dirk E. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (23) :4293-4297

[3] Metal-organic frameworks as high-potential adsorbents for liquid-phase separations of olefins, alkylnaphthalenes and dichlorobenzenes [J].

Alaerts, Luc ;

Maes, Michael ;

van der Veen, Monique A. ;

Jacobs, Pierre A. ;

De Vos, Dirk E. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2009, 11 (16) :2903-2911

[4] INFRARED SPECTROSCOPIC INVESTIGATIONS OF ZEOLITES AND ADSORBED MOLECULES .3. AROMATIC HYDROCARBONS [J].

ANGELL, CL ;

HOWELL, MV .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1968, 28 (02) :279-&

[5]

[Anonymous], 2005, Gas Adsorption Equilibria: Experimental Methods and Adsorption Isotherms

[6]

[Anonymous], 1996, HDB CHEM PHYS

[7]

[Anonymous], 1952, SEL VAL PROP HYDR RE

[8]

[Anonymous], 2008, KIRK OTHM ENC CHEM T

[9]

[Anonymous], 1975, SEL VAL PROP CHEM CO

[10]

Auerbach S. M., 2003, HDB ZEOLITE SCI TECH

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