Controlled crystallization of mixed-ligand complexes of 1,3-bis(4-pyridyl)propane-N,N′-dioxide with metal(II) thiocyanates:: isostructurality in coordination networks bearing different mono- and di-nuclear nodes

被引:27
作者
Zhang, LP
Lu, WJ
Mak, TCW [1 ]
机构
[1] Chinese Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
[2] Wuyi Univ, Dept Environm Chem & Engn, Jiangmen, Guangdong Prov, Peoples R China
关键词
D O I
10.1039/b307604k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The new flexible spacer ligand 1,3-bis(4-pyridyl) propane-N, N'-dioxide forms three classes of isomorphous compounds with metal(II) thiocyanates at controlled ligand - metal molar ratios, and its mu(3)-O,O,O' mode leads to a pair of coordination networks having the same (4, 4) topological characteristics but different mono- and di-nuclear nodes.
引用
收藏
页码:2830 / 2831
页数:2
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