Synthesis and structural characterization of a stable dimeric boron(II) dication

被引：66

作者：

Dinda, Rupam ^{[1
]}

Ciobanu, Oxana ^{[1
]}

Wadepohl, Hubert ^{[1
]}

Hubner, Olaf ^{[1
]}

Acharyya, Rama ^{[1
]}

Himmel, Hans-Jorg ^{[1
]}

机构：

[1] Univ Heidelberg, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 47期

关键词：

boron; cations; quantum chemistry; subvalent compounds;

D O I：

10.1002/anie.200703616

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Bor-muda triangle: The first representative of a new type of boron cation is formed as the product of the reaction between B2Cl2(NMe2)2 and the guanidine derivative hppH (see scheme). The B-B bond length is typical for a single bond, and both boron atoms and the hpp nitrogen atoms bound directly to them form a trigonal prism. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9110 / 9113

页数：4

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