Supramolecular assembly of light harvesting porphyrin hexamer

被引:39
作者
Shinmori, H [1 ]
Kajiwara, T [1 ]
Osuka, A [1 ]
机构
[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Kyoto 6068502, Japan
关键词
D O I
10.1016/S0040-4039(01)00520-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Pentameric porphyrin hosts, in which a TPP type porphyrin was attached to four OEP type zinc porphyrins through a 1,3-phenylene spacer, were synthesized. Its spectroscopic investigations suggest that the host binds a one molecule of meso-tetrapyridyl porphyrin by coordination to the central metals of the peripheral four zinc porphyrins to constitute a light harvesting porphyrin hexameric assembly. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3617 / 3620
页数:4
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