Migration of semiflexible polymers in microcapillary flow

被引:67
作者
Chelakkot, Raghunath [1 ]
Winkler, Roland G. [1 ]
Gompper, Gerhard [1 ]
机构
[1] Forschungszentrum Julich, Inst Festkorperforsch, D-52425 Julich, Germany
关键词
MULTIPARTICLE COLLISION DYNAMICS; SHEAR-INDUCED MIGRATION; SIMULATION; CHAIN; HYDRODYNAMICS; TRANSPORT;
D O I
10.1209/0295-5075/91/14001
中图分类号
O4 [物理学];
学科分类号
070305 [高分子化学与物理];
摘要
The non-equilibrium structural and dynamical properties of a semiflexible polymer confined in a cylindrical microchannel and exposed to a Poiseuille flow is studied by mesoscale hydrodynamic simulations. For a polymer with a length half of its persistence length, large variations in orientation and conformations are found as a function of radial distance and flow strength. In particular, the polymer exhibits U-shaped conformations near the channel center. Hydrodynamic interactions lead to strong cross-streamline migration. Outward migration is governed by the polymer orientation and the corresponding anisotropy in its diffusivity. Strong tumbling motion is observed, with a tumbling time which exhibits the same dependence on Peclet number as a polymer in shear flow. Copyright (C) EPLA, 2010
引用
收藏
页数:6
相关论文
共 32 条
[1]
MIGRATION OF MACROMOLECULES UNDER FLOW - THE PHYSICAL ORIGIN AND ENGINEERING IMPLICATIONS [J].
AGARWAL, US ;
DUTTA, A ;
MASHELKAR, RA .
CHEMICAL ENGINEERING SCIENCE, 1994, 49 (11) :1693-1717
[2]
Simulation of a single polymer chain in solution by combining lattice Boltzmann and molecular dynamics [J].
Ahlrichs, P ;
Dünweg, B .
JOURNAL OF CHEMICAL PHYSICS, 1999, 111 (17) :8225-8239
[3]
Relaxation of stretched DNA in slitlike confinement [J].
Balducci, A. ;
Hsieh, C. -C. ;
Doyle, P. S. .
PHYSICAL REVIEW LETTERS, 2007, 99 (23)
[4]
Mesoscale simulations of polymer dynamics in microchannel flows [J].
Cannavacciuolo, L. ;
Winkler, R. G. ;
Gompper, G. .
EPL, 2008, 83 (03)
[5]
Multi-Particle Collision Dynamics: A Particle-Based Mesoscale Simulation Approach to the Hydrodynamics of Complex Fluids [J].
Gompper, G. ;
Ihle, T. ;
Kroll, D. M. ;
Winkler, R. G. .
ADVANCED COMPUTER SIMULATION APPROACHES FOR SOFT MATTER SCIENCES III, 2009, 221 :1-87
[6]
Cell-level canonical sampling by velocity scaling for multiparticle collision dynamics simulations [J].
Huang, C. C. ;
Chatterji, A. ;
Sutmann, G. ;
Gompper, G. ;
Winkler, R. G. .
JOURNAL OF COMPUTATIONAL PHYSICS, 2010, 229 (01) :168-177
[7]
Ihle T, 2001, PHYS REV E, V63, DOI 10.1103/PhysRevE.63.020201
[8]
Shear-induced migration in flowing polymer solutions: Simulation of long-chain deoxyribose nucleic acid in microchannels [J].
Jendrejack, RM ;
Schwartz, DC ;
de Pablo, JJ ;
Graham, MD .
JOURNAL OF CHEMICAL PHYSICS, 2004, 120 (05) :2513-2529
[9]
DNA dynamics in a microchannel [J].
Jendrejack, RM ;
Dimalanta, ET ;
Schwartz, DC ;
Graham, MD ;
de Pablo, JJ .
PHYSICAL REVIEW LETTERS, 2003, 91 (03)
[10]
MULTIPARTICLE COLLISION DYNAMICS: SIMULATION OF COMPLEX SYSTEMS ON MESOSCALES [J].
Kapral, Raymond .
ADVANCES IN CHEMICAL PHYSICS, VOL 140, 2008, 140 :89-146