Optical sensing of aromatic hydrocarbons using Langmuir-Blodgett films of a Schiff base co-ordination polymer

被引:17
作者
Wilde, JN
Nagel, J
Petty, MC [1 ]
机构
[1] Univ Durham, Sch Engn, Durham DH1 3LE, England
[2] Univ Durham, Ctr Mol Elect, Durham DH1 3LE, England
[3] Inst Polymerforsch Dresden EV, Dresden, Germany
基金
英国工程与自然科学研究理事会;
关键词
co-ordination polymer; Langmuir-Blodgett (LB) films; surface plasmon resonance (SPR); vapour sensing; aromatic hydrocarbons;
D O I
10.1016/S0040-6090(98)00751-2
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Aromatic hydrocarbon sensing has been successfully demonstrated using surface plasmon resonance (SPR) with Langmuir-Blodgett (LB) films of a 5,5'-methylenebis (N-hexadecylsaliclidenamine) Schiff base complex. The LB layers were exposed to concentrations of benzene, toluene, ethanol and water vapours. This resulted in a reversible shift in the resonance depth and position of the SPR curves. The co-ordination polymer was found to be most sensitive to benzene and could reliably detect concentrations of this vapour down to 100 vapour parts per million. (C) 1998 Published by Elsevier Science S.A. All rights reserved.
引用
收藏
页码:726 / 729
页数:4
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