Palladium catalysts supported on oligomeric aramides in the liquid-phase hydrogenation of phenylacetylene

被引：28

作者：

Arena, F ^{[1
]}

Cum, G ^{[1
]}

Gallo, R ^{[1
]}

Parmaliana, A ^{[1
]}

机构：

[1] UNIV MESSINA,DIPARTIMENTO CHIM IND,I-98100 MESSINA,ITALY

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1996年 / 110卷 / 03期

关键词：

palladium catalysts; organic matrices; aromatic oligoamides; phenylacetylene hydrogenation; metal dispersion; turnover frequency;

D O I：

10.1016/1381-1169(96)00188-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The catalytic behaviour of palladium supported on oligomeric aramides has been investigated in the liquid phase selective hydrogenation of phenylacetylene to styrene, by comparison with conventional Pd-supported systems, such as Pd/carbon, Pd/Al2O3 and Pd/SiO2. The influences of the reduction temperature and metal loading on the activity/selectivity behaviour of the title reaction are explained in terms of different reducibility patterns of the catalysts, as well as in the light of a peculiar support effect of the organic matrix on Pd particles.

引用

页码：235 / 242

页数：8