Lewis acid-base adducts of pentamethylcyclopentadienylgallium with trivalent group 13-element compounds

被引：45

作者：

Jutzi, P ^{[1
]}

Neumann, B ^{[1
]}

Reumann, G ^{[1
]}

Schebaum, LO ^{[1
]}

Stammler, HG ^{[1
]}

机构：

[1] Univ Bielefeld, Fak Chem, D-4800 Bielefeld, Germany

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 13期

关键词：

D O I：

10.1021/om010132g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the reaction of (eta (5)-pentamethylcylopentadienyl)gallium (Cp*Ga) with B(CsF5)(3), (GaBu3)-Bu-t, and Cp*GaX2 (X = Cl, I) the new complexes Cp*GaB(C6F5)(3), 1, Cp*(GaGaBu3)-Bu-t, 2, and Cp*GaGa(X)(2)Cp* (X = Cl, 3; I, 4), respectively, were obtained. Alternatively, complex 3 was formed in the reaction of Cp*Ga with InCl. Compounds 1-4 were characterized by analytical and spectroscopic methods. In addition, X-ray crystal structure analyses of 1, 3, and 4 were performed.

引用

页码：2854 / 2858

页数：5

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