Comment on "Gas-phase photochemistry of the photoactive yellow protein chromophore trans-p-coumaric acid

被引：20

作者：

de Groot, M ^{[1
]}

Buma, WJ ^{[1
]}

机构：

[1] Univ Amsterdam, Fac Sci, Vant Hoff Inst Mol Sci, NL-1018 WV Amsterdam, Netherlands

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2005年 / 109卷 / 27期

关键词：

D O I：

10.1021/jp052128e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The gas-phase photochemistry of the photoactive yellow protein (PYP) chromophore trans-p-coumaric acid was presented. The vibrationally resolved laser-induced fluorescence excitation and emission spectra of this chromophore was studied. The protein plays an essential role driving the photoisomerization of the chromophore. The excitation spectrum of trans-p-coumaric acid (trans-pCA) with mass-resolved resonance enhanced two-photon ionization spectroscopy (MR-RE2PI) was measured. It was concluded that the fluorescence excitation and dispersed emission spectra must be attributed to p-vinylphenol (pVP) and not to pCA.

引用

页码：6135 / 6136

页数：2

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