Spontaneous macrocyclization via recombination of a Schiff-base linkage

被引：25

作者：

Houjou, H ^{[1
]}

Nagawa, Y ^{[1
]}

Hiratani, K ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Nanoarchitecton Res Ctr, Tsukuba, Ibaraki 3058562, Japan

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 23期

关键词：

D O I：

10.1016/S0040-4039(01)00516-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A macrocyclic compound that has two salenH(2) moieties was synthesised via recombination of an acyclic Schiff base in quite high yield, and was characterized by X-ray crystallography. The recombination occurred in a slow diffusion system of chloroform-methanol, where the starting material may spontaneously form a molecular assembly suitable for the subsequent reaction. This assumption was supported by the crystal structure of an analogue of the acyclic Schiff base. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：3861 / 3863

页数：3

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