A stereoselective isomerization of allyl silyl ethers to (E)- or (Z)-silyl enol ethers using cationic iridium complexes

被引：41

作者：

Ohmura, T ^{[1
]}

Shirai, Y ^{[1
]}

Yamamoto, Y ^{[1
]}

Miyaura, N ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Engn, Div Mol Chem, Sapporo, Hokkaido 0608628, Japan

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 13期

关键词：

D O I：

10.1039/a802760i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A cationic iridium complex, prepared via the hydrogenation of [Ir(cod)(2)]PF6-2PPr(3) is found to be an excellent catalyst for the stereoselective isomerization of primary allyl silyl ethers to (E)-enol ethers and secondary allyl ethers to (Z)-enol ethers.

引用

页码：1337 / 1338

页数：2

共 7 条

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