A stereoselective isomerization of allyl silyl ethers to (E)- or (Z)-silyl enol ethers using cationic iridium complexes

被引:41
作者
Ohmura, T [1 ]
Shirai, Y [1 ]
Yamamoto, Y [1 ]
Miyaura, N [1 ]
机构
[1] Hokkaido Univ, Grad Sch Engn, Div Mol Chem, Sapporo, Hokkaido 0608628, Japan
关键词
D O I
10.1039/a802760i
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A cationic iridium complex, prepared via the hydrogenation of [Ir(cod)(2)]PF6-2PPr(3) is found to be an excellent catalyst for the stereoselective isomerization of primary allyl silyl ethers to (E)-enol ethers and secondary allyl ethers to (Z)-enol ethers.
引用
收藏
页码:1337 / 1338
页数:2
相关论文
共 7 条