A new method for cross-metathesis of terminal olefins

被引：55

作者：

O'Leary, DJ ^{[1
]}

Blackwell, HE ^{[1
]}

Washenfelder, RA ^{[1
]}

Grubbs, RH ^{[1
]}

机构：

[1] CALTECH, Arnold & Mabel Beckman Labs Chem Synthesis, Div Chem & Chem Engn, Pasadena, CA 91125 USA

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 41期

关键词：

D O I：

10.1016/S0040-4039(98)01647-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new method for the cross-metathesis of terminal olefins is described. Treatment of terminal olefins with 1-2 equivalents of a symmetric disubstituted cis or trans olefin and 5 mol% Cl-2(PCy3)(2)Ru=CHPh (1) in dichloromethane generates the desired cross-metathesis products in good yield. (C) 1998 Elsevier Science Ltd. AII rights reserved.

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收藏

页码：7427 / 7430

页数：4

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