Infra-red emission characterization of polycrystalline diamond films

被引:7
作者
Ayres, VM
McCormick, T
Alexander, WB
Vestyck, DJ
Butler, JE
Spiberg, P
机构
[1] Michigan State Univ, Dept Elect Engn, E Lansing, MI 48824 USA
[2] Harris Semicond Inc, Analyt Serv, Palm Bay, FL 32905 USA
[3] MEMC Elect Mat Inc, St Peters, MO 63376 USA
[4] Geocenters Inc, Ft Washington, MD 20744 USA
[5] USN, Res Lab, Div Chem, Washington, DC 20375 USA
[6] ECR Corp, San Diego, CA 92121 USA
关键词
infra-red; defect; photoluminescence; Raman spectroscopy;
D O I
10.1016/S0925-9635(97)00320-8
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Infra-red emission has been used to characterize polycrystalline diamond films of differing qualities, produced by de arcjet chemical vapor deposition. Intrinsic and defect-induced bands were observed from samples heated in a low emissivity cell using Fourier Transform Infra-red spectroscopy (FTIR). In addition, the IR emission and absorption spectra of polished IIa and Ib single crystal diamonds were measured to compare the intrinsic and nitrogen-induced absorption and emission bands. Emission features observed included the intrinsic two phonon bands, defect-induced one phonon bands (from symmetry breaking), nitrogen-related bands, and CH stretching bands. Complementary information on the quality and defects in the samples was provided using photoluminescence and Raman spectroscopies. (C) 1998 Elsevier Science S.A.
引用
收藏
页码:789 / 793
页数:5
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