Electrooxidation of ethylene glycol on a platinum doped polyaniline electrode

被引:57
作者
Ficicioglu, F
Kadirgan, F [1 ]
机构
[1] Tech Univ Istanbul, Fen Edebiyat Fak, Istanbul, Turkey
[2] TUBITAK, Marmara Res Ctr, Gebze Kocaeli, Turkey
来源
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1998年 / 451卷 / 1-2期
关键词
polyaniline; electrooxidation; electrodes;
D O I
10.1016/S0022-0728(98)00086-2
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The oxidation of ethylene glycol was investigated on platinum doped polyaniline electrodes. It is found that polyaniline films can be used as a convenient conducting substrate for the electrooxidation of ethylene glycol. Optimum experimental conditions for the preparation of the catalytic system are determined. Current densities obtained with modified polyaniline electrodes for the oxidation of ethylene glycol in acidic media are comparable to those on bulls platinum. It is found that the polyaniline film thickness has no effect on the kinetics of the ethylene glycol oxidation reaction. (C) 1998 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:95 / 99
页数:5
相关论文
共 7 条
[1]   Electrocatalytic properties of platinum particles incorporated with polypyrrole films in D-glucose oxidation in phosphate media [J].
Becerik, I ;
Kadirgan, F .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1997, 436 (1-2) :189-193
[2]   THE PROPERTIES OF PALLADIUM ELECTRODES FOR ELECTROOXIDATION OF ETHYLENE-GLYCOL [J].
DALBAY, N ;
KADIRGAN, F .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 296 (02) :559-569
[3]  
Ficicioglu F, 1997, J ELECTROANAL CHEM, V430, P179
[4]   OXIDATION OF FORMIC-ACID AT POLYANILINE-COATED AND MODIFIED-POLYANILINE-COATED ELECTRODES [J].
GHOLAMIAN, M ;
SUNDARAM, J ;
CONTRACTOR, AQ .
LANGMUIR, 1987, 3 (05) :741-744
[5]   ELECTROCATALYTIC OXIDATION OF METHANOL BY ASSEMBLIES OF PLATINUM TIN CATALYST PARTICLES IN A CONDUCTING POLYANILINE MATRIX [J].
HABLE, CT ;
WRIGHTON, MS .
LANGMUIR, 1991, 7 (07) :1305-1309
[6]   ELECTRODEPOSITION OF PLATINUM MICROPARTICLES INTO POLYANILINE FILMS WITH ELECTROCATALYTIC APPLICATIONS [J].
KOST, KM ;
BARTAK, DE ;
KAZEE, B ;
KUWANA, T .
ANALYTICAL CHEMISTRY, 1988, 60 (21) :2379-2384
[7]  
LABORDE H, 1994, J APPL ELECTROCHEM, V24, P219