Fe/Si multi-layer thin film anodes for lithium rechargeable thin film batteries

被引:79
作者
Kim, JB [1 ]
Lee, HY [1 ]
Lee, KS [1 ]
Lim, SH [1 ]
Lee, SM [1 ]
机构
[1] Kangwon Natl Univ, Dept Adv Mat Sci & Engn, Chunchon 200701, South Korea
关键词
thin film battery; Fe-Si multi-layer thin film; anodes film; cycling performance;
D O I
10.1016/S1388-2481(03)00120-6
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Fe/Si multi-layer thin films were prepared by alternate deposition using an electron-beam evaporation method. Electrochemical results through galvanostatic charge-discharge experiments are presented. It appears that the volumetric expansion of silicon during cycling can be effectively suppressed by forming a Fe layer between Si layers. The electrochemical characteristics of Fe/Si multi-layer film electrode can be controlled by the thickness, and number of stacked Si layers, and post-annealing. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:544 / 548
页数:5
相关论文
共 17 条
  • [1] Preferred orientation of polycrystalline LiCoO2 films
    Bates, JB
    Dudney, NJ
    Neudecker, BJ
    Hart, FX
    Jun, HP
    Hackney, SA
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (01) : 59 - 70
  • [2] Structure and properties of sequentially sputtered molybdenum-tin films
    Dahn, JR
    Turner, RL
    Mao, O
    Dunlap, RA
    George, AE
    Buckett, MM
    McClure, DJ
    Krause, LJ
    [J]. THIN SOLID FILMS, 2002, 408 (1-2) : 111 - 122
  • [3] DUNDNEY NJ, 1999, J ELECTROCHEM SOC, V146, P2455
  • [4] AMORPHOUS TI-SI ALLOY FORMED BY INTERDIFFUSION OF AMORPHOUS SI AND CRYSTALLINE TI MULTILAYERS
    HOLLOWAY, K
    SINCLAIR, R
    [J]. JOURNAL OF APPLIED PHYSICS, 1987, 61 (04) : 1359 - 1364
  • [5] A THIN-FILM SOLID-STATE MICROBATTERY
    JONES, SD
    AKRIDGE, JR
    [J]. SOLID STATE IONICS, 1992, 53 (pt 1) : 628 - 634
  • [6] KAMP BAB, 1981, J ELECTROCHEM SOC, V128, P725
  • [7] THIN-FILM SOLID ELECTROLYTE AND ITS APPLICATION TO SECONDARY LITHIUM CELL
    KANEHORI, K
    MATSUMOTO, K
    MIYAUCHI, K
    KUDO, T
    [J]. SOLID STATE IONICS, 1983, 9-10 (DEC) : 1445 - 1448
  • [8] Graphite-FeSi alloy composites as anode materials for rechargeable lithium batteries
    Lee, HY
    Lee, SM
    [J]. JOURNAL OF POWER SOURCES, 2002, 112 (02) : 649 - 654
  • [9] Performance of tin-containing thin-film anodes for rechargeable thin-film batteries
    Lee, SJ
    Lee, HY
    Jeong, SH
    Baik, HK
    Lee, SM
    [J]. JOURNAL OF POWER SOURCES, 2002, 111 (02) : 345 - 349
  • [10] Amorphous lithium nickel vanadate thin-film anodes for rechargeable lithium microbatteries
    Lee, SJ
    Lee, HY
    Ha, TS
    Baik, HK
    Lee, SM
    [J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2002, 5 (06) : A138 - A140