Performance of tin-containing thin-film anodes for rechargeable thin-film batteries

被引：34

作者：

Lee, SJ

Lee, HY

Jeong, SH

Baik, HK

Lee, SM ^{[1
]}

机构：

[1] Kangweon Natl Univ, Dept Adv Mat Sci & Engn, Chunchon 200701, Kangwon Do, South Korea

[2] Yonsei Univ, Dept Met Engn, Seoul 120749, South Korea

来源：

JOURNAL OF POWER SOURCES | 2002年 / 111卷 / 02期

关键词：

thin film; anode; tin-alloying; microbattery; cycling performance;

D O I：

10.1016/S0378-7753(02)00344-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Thin film, Sn, Cu-Sn and Sn-Zr-(O) anodes for microbatteries are deposited on a copper substrate by radio frequency (rf)-magnetron sputtering at room temperature. Charge-discharge characteristics are compared. It appears that the alloying of Sn with Cu or Zr improves the cycling performance. The best cycling efficiency is obtained when Sn is alloyed with Zr. The effects of alloying elements on the electrochemical properties on the thin film are discussed. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：345 / 349

页数：5

共 13 条

[1] Thin-film crystalline SnO2-lithium electrodes
Brousse, T
Retoux, R
Herterich, U
Schleich, DM
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (01) : 1 - 4
[2] On the aggregation of tin in SnO composite glasses caused by the reversible reaction with lithium
Courtney, IA
McKinnon, WR
Dahn, JR
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (01) : 59 - 68
[3] Electrochemical and in situ x-ray diffraction studies of the reaction of lithium with tin oxide composites
Courtney, IA
Dahn, JR
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (06) : 2045 - 2052
[4] Lithium alloy negative electrodes formed from convertible oxides
Huggins, RA
[J]. SOLID STATE IONICS, 1998, 113 : 57 - 67
[5] HUGGINS RA, 1999, HDB BATTERY MAT, pCH4
[6] Tin-based amorphous oxide: A high-capacity lithium-ion-storage material
Idota, Y
Kubota, T
Matsufuji, A
Maekawa, Y
Miyasaka, T
[J]. SCIENCE, 1997, 276 (5317) : 1395 - 1397
[7] LixCu6Sn5 (0<x<13):: An intermetallic insertion electrode for rechargeable lithium batteries
Kepler, KD
Vaughey, JT
Thackeray, MM
[J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 1999, 2 (07) : 307 - 309
[8] Copper-tin anodes for rechargeable lithium batteries: an example of the matrix effect in an intermetallic system
Kepler, KD
Vaughey, JT
Thackeray, MM
[J]. JOURNAL OF POWER SOURCES, 1999, 81 : 383 - 387
[9] Effect of Si addition to thin-film SnO2 microbattery anodes on cycling performance
Kim, YI
Lee, WH
Moon, HS
Ji, KS
Seong, SH
Park, JW
[J]. JOURNAL OF POWER SOURCES, 2001, 101 (02) : 253 - 258
[10] In situ X-ray study of the electrochemical reaction of Li with η′-Cu6Sn5
Larcher, D
Beaulieu, LY
MacNeil, DD
Dahn, JR
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (05) : 1658 - 1662

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