Resonant effects on rate constants in the presence of fluctuating barriers

被引：5

作者：

Gaveau, B ^{[1
]}

Moreau, M ^{[1
]}

机构：

[1] UNIV PARIS 06,PHYS THEOR LIQUIDES LAB,F-75252 PARIS 05,FRANCE

来源：

PHYSICS LETTERS A | 1996年 / 211卷 / 06期

关键词：

D O I：

10.1016/0375-9601(96)00011-4

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We study a very simple model for the cage effect for a chemical reaction in a solvent. The effect of the solvent is represented by two fluctuating barriers together with a standard diffusion and deexcitation process. We prove the existence of a resonant effect for the overall rate constant.

引用

页码：331 / 338

页数：8

共 23 条

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