The crystal structure of bis(η5-cyclopentadienyl)diazido-vanadium(IV)

被引：9

作者：

Honzícek, J

Erben, M

Císarová, I

Vinklárek, J

机构：

[1] Univ Pardubice, Dept Gen & Inorgan Chem, Pardubice 53210, Czech Republic

[2] Charles Univ Prague, Dept Inorgan Chem, CR-12840 Prague 2, Czech Republic

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2005年 / 19卷 / 01期

关键词：

bent metallocene; vanadocene; pseudohalide; crystal structure; azide;

D O I：

10.1002/aoc.762

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The crystal structure of the cyclopentadienyl vanadocene complex (n(5)-C5H5)(2)V(N-3)(2) was determined. The molecule has a typical bent metallocene structure in which two n(5)-bonded cyclopentadienyl rings and two nitrogen atoms of azide ligands occupy the pseudotetrahedral coordination sites around the vanadium(IV) center. Copyright (C) 2004 John Wiley Sons, Ltd.

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页码：102 / 103

页数：2

相关论文

共 14 条

[1] SIR92 - a program for automatic solution of crystal structures by direct methods [J].

ALTOMARE, A ;

CASCARANO, G ;

GIACOVAZZO, G ;

GUAGLIARDI, A ;

BURLA, MC ;

POLIDORI, G ;

CAMALLI, M .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435

[2]

ANDERSON SJ, 1974, J CHEM SOC CHEM COMM, P996

[3] BONDING PATTERNS IN METALLOCENE PSEUDOHALIDE COMPLEXES [J].

BURMEISTER, JL ;

DEARDORF.EA ;

JENSEN, A ;

CHRISTIA.VH .

INORGANIC CHEMISTRY, 1970, 9 (01) :58-+

[4]

DEGIL ER, 1977, ACTA CRYSTALLOGR B, V33, P2653

[5] PSEUDOHALIDE AND CHELATE COMPLEXES OF BIS(CYCLOPENTADIENYL)VANADIUM(4) [J].

DOYLE, G ;

TOBIAS, RS .

INORGANIC CHEMISTRY, 1968, 7 (12) :2479-&

[6] μ-Oxo-bis[azidobis(η5-cyclopentadienyl)-titanium(IV)] [J].

Honzícek, J ;

Vinklárek, J ;

Erben, M ;

Císarová, I .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 :M1090-M1091

[7]

HONZICEK J, 2004, IN PRESS J APPL ORGA, V18

[8] SYNTHESIS AND CHARACTERIZATION OF MIXED CYANOTHIOCYANATE AND CYANOSELENOCYANATE COMPLEXES OF BIS(CYCLOPENTADIENYL)-TITANIUM, BIS(CYCLOPENTADIENYL)-VANADIUM AND BIS(CYCLOPENTADIENYL)-CHROMIUM [J].

MORAN, M ;

FERNANDEZ, V .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 165 (02) :215-223

[9] Processing of X-ray diffraction data collected in oscillation mode [J].

Otwinowski, Z ;

Minor, W .

MACROMOLECULAR CRYSTALLOGRAPHY, PT A, 1997, 276 :307-326

[10] Synthesis, characterization, and structures of new titanocene isoselenocyanato complexes [J].

Raptopoulou, CP ;

Tzavellas, N ;

Klouras, N .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1996, 622 (08) :1387-1391