Glory-scattering measurement of water-noble-gas interactions: The birth of the hydrogen bond

被引：101

作者：

Aquilanti, V

Cornicchi, E

Teixidor, MM

Saendig, N

Pirani, F

Cappelletti, D ^{[1
]}

机构：

[1] Univ Perugia, Dipartimento Ingn Civile & Ambientale, I-06100 Perugia, Italy

[2] INFM, Perugia, Italy

[3] Univ Perugia, Dipartimento Chim, I-06100 Perugia, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 16期

关键词：

ab initio calculations; charge transfer; hydrogen bonds; molecular beam scattering; water;

D O I：

10.1002/anie.200462704

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Incipient hydrogen bonds in water-noble gas complexes, which increase in strength from He to Xe, are manifested by progressive alignment along the O-H bond (see picture) according to ab initio calculations. The strength of the interaction in excess of that expected for pure van der Waals forces was assessed experimentally by molecular beam scattering. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

收藏

页码：2356 / 2360

页数：5

相关论文

共 24 条

[1] Electronic basis of improper hydrogen bonding: A subtle balance of hyperconjugation and rehybridization [J].

Alabugin, IV ;

Manoharan, M ;

Peabody, S ;

Weinhold, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (19) :5973-5987

[2] Weak C-H•••O and C-H•••F-C hydrogen bonds in the oxirane-trifluoromethane dimer [J].

Alonso, JL ;

Antolínez, S ;

Blanco, S ;

Lesarri, A ;

López, JC ;

Caminati, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (10) :3244-3249

[3] Range and strength of interatomic forces: Dispersion and induction contributions to the bonds of dications and of ionic molecules [J].

Aquilanti, V ;

Cappelletti, D ;

Pirani, F .

CHEMICAL PHYSICS, 1996, 209 (2-3) :299-311

[4] VELOCITY DEPENDENCE OF COLLISIONAL ALIGNMENT OF OXYGEN MOLECULES IN GASEOUS EXPANSIONS [J].

AQUILANTI, V ;

ASCENZI, D ;

CAPPELLETTI, D ;

PIRANI, F .

NATURE, 1994, 371 (6496) :399-402

[5] Molecular beam scattering of nitrogen molecules in supersonic seeded beams: A probe of rotational alignment [J].

Aquilanti, V ;

Ascenzi, D ;

Cappelletti, D ;

Fedeli, R ;

Pirani, F .

JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (41) :7648-7656

[6] Orienting and aligning molecules for stereochemistry and photodynamics [J].

Aquilanti, V ;

Bartolomei, M ;

Pirani, F ;

Cappelletti, D ;

Vecchiocattivi, F ;

Shimizu, Y ;

Kasai, T .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2005, 7 (02) :291-300

[7] SCATTERING OF ROTATIONALLY ALIGNED OXYGEN MOLECULES AND THE MEASUREMENT OF ANISOTROPIES OF VAN-DER-WAALS FORCES [J].

AQUILANTI, V ;

ASCENZI, D ;

CAPPELLETTI, D ;

FRANCESCHINI, S ;

PIRANI, F .

PHYSICAL REVIEW LETTERS, 1995, 74 (15) :2929-2932

[8] Scattering of aligned molecules.: The potential energy surfaces for the Kr-O2 and Xe-O2 systems [J].

Aquilanti, V ;

Ascenzi, D ;

Cappelletti, D ;

de Castro, M ;

Pirani, F .

JOURNAL OF CHEMICAL PHYSICS, 1998, 109 (10) :3898-3910

[9] HIGH-RESOLUTION TOTAL DIFFERENTIAL CROSS-SECTIONS FOR SCATTERING OF HELIUM BY O-2, N-2, AND NO [J].

BENEVENTI, L ;

CASAVECCHIA, P ;

VOLPI, GG .

JOURNAL OF CHEMICAL PHYSICS, 1986, 85 (12) :7011-7029

[10] Elastic and rotationally inelastic differential cross sections for He+H2O collisions [J].

Brudermann, J ;

Steinbach, C ;

Buck, U ;

Patkowski, K ;

Moszynski, R .

JOURNAL OF CHEMICAL PHYSICS, 2002, 117 (24) :11166-11174