Dithienophosphole-capped π-conjugated oligomers

被引：19

作者：

Durben, Stefan ^{[1
]}

Linder, Thomas ^{[1
]}

Baumgartner, Thomas ^{[1
]}

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

来源：

NEW JOURNAL OF CHEMISTRY | 2010年 / 34卷 / 08期

基金：

加拿大创新基金会; 加拿大自然科学与工程研究理事会;

关键词：

PHOTOPHYSICAL PROPERTIES; ELECTRON SYSTEMS; BUILDING-BLOCK; BAND-GAP; LUMINESCENT; POLYMERS; SEMICONDUCTORS; ORGANIZATION; COPOLYMERS; EMISSION;

D O I：

10.1039/c0nj00026d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of a 2-monobrominated dithieno[3,2-b:2',3'-d]phosphole has opened the access to a series of highly luminescent pi-conjugated oligomers that link two dithienophosphole units via a variety of aromatic spacers. The nature of the linking mode was found to have a significant impact on the photophysical properties of the system as a whole, either considerably improving the molar absorptivity of the new extended chromophores, or providing luminescent materials with red-shifted emission features and substantial photoluminescence quantum yields.

引用

页码：1585 / 1592

页数：8

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