Two-photon absorption properties of heterafluorenes and spirobiheterafluorenes bearing aminostyryl arms

被引:18
作者
Agou, Tomohiro [1 ]
Hossain, Md. Delwar [1 ]
Kawashima, Takayuki [1 ]
Kamada, Kenji [2 ]
Ohta, Koji [2 ]
机构
[1] Univ Tokyo, Dept Chem, Grad Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan
[2] AIST, Natl Inst Adv Ind Sci & Technol AIST, Photon Res Inst, Osaka 5638577, Japan
关键词
NONLINEAR-OPTICAL PROPERTIES; QUADRUPOLAR; DERIVATIVES; MOLECULES; DESIGN; DONOR;
D O I
10.1039/b912745c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A phosphoniafluorene and a spirobiphosphoniafluorene bearing 4-(diethylamino)styryl groups were synthesized. These compounds exhibited bathochromically shifted absorption and emission, compared with their silicon analogues, because of the strong acceptor property of the phosphonium core. They also showed enhanced two-photon absorptions at around 930 nm.
引用
收藏
页码:6762 / 6764
页数:3
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