Iron-catalyzed asymmetric epoxidation of aromatic alkenes using hydrogen peroxide

被引：193

作者：

Gelalcha, Feyissa Gadissa ^{[1
]}

Bitterlich, Bianca ^{[1
]}

Anilkumar, Gopinathan ^{[1
]}

Tse, Man Kin ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock eV, Leibniz Inst Katalyse, D-18059 Rostock, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 38期

关键词：

asymmetric catalysis; epoxidation; hydrogen peroxide; iron;

D O I：

10.1002/anie.200701235

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Ironing out the wrinkles: Highly enantioselective catalytic asymmetric epoxidation of aromatic alkenes with hydrogen peroxide proceeds smoothly in the presence of a catalyst system consisting of ferric hexahydrate, pyridine-2,6-dicarboxylic acid, and the novel chiral ligand 1 in 2-methylbutane-2-ol solvent at room temperature within 1 h (see scheme; Bn = benzyl). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7293 / 7296

页数：4

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