RhI-catalyzed hydration of organonitriles under ambient conditions

被引：175

作者：

Goto, Akihiro ^{[1
]}

Endo, Kohei ^{[1
]}

Saito, Susumu ^{[1
,2
]}

机构：

[1] Nagoya Univ, Dept Chem, Grad Sch Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[2] Nagoya Univ, Inst Adv Res, Nagoya, Aichi 4648601, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 19期

关键词：

amides; homogeneous catalysis; hydration; nitriles; rhodium;

D O I：

10.1002/anie.200800366

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Presented) New scoop on scope and selectivity: The hydration of organonitriles catalyzed by a RhI(OMe) species under nearly pH-neutral and ambient conditions (25°C, 1 atm) is chemoselective and high-yielding (93 to 99%), has a broad substrate scope, and may thus be complementary to enzymatic hydration methods for the introduction of a terminal amido group (CONH2) onto a carbon chain. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3607 / 3609

页数：3

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