Novel smart ligand for immobilizing a highly efficient Rh-catalyst

被引：10

作者：

Lee, JK ^{[1
]}

Yoon, TJ

Chung, YK

机构：

[1] Seoul Natl Univ, Sch Chem, Seoul 151747, South Korea

[2] Seoul Natl Univ, Ctr Mol Catalysis, Seoul 151747, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 13期

关键词：

D O I：

10.1039/b101506k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel highly efficient Rh-based catalysts with a good regioselectivity in olefin hydroformylation have been prepared by deliberately choosing 11-mercaptoundecanoic acid as a ligating molecule to [Rh(cod)Cl](2) (cod = cyclooctadiene) and a simple recovery process for their recycling was investigated.

引用

收藏

页码：1164 / 1165

页数：2

相关论文

共 14 条

[1] A new, efficient, and in some cases highly regioselective water-soluble polymer rhodium catalyst for olefin hydroformylation [J].

Ajjou, AN ;

Alper, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (07) :1466-1468

[2] Hydroformylation of styrene catalyzed by a rhodium thiolate binuclear catalyst supported on a cationic exchange resin [J].

Balué, J ;

Bayón, JC .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 137 (1-3) :193-203

[3] A novel water-soluble rhodium-poly(enolate-co-vinyl alcohol-co-vinyl acetate) catalyst for the hydroformylation of olefins [J].

Chen, JH ;

Alper, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (05) :893-895

[4] Homogeneous and biphasic autoxidation of tetralin catalyzed by transition metal salts and complexes [J].

Chung, YM ;

Kang, KK ;

Ahn, WS ;

Lim, PK .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 137 (1-3) :23-29

[5]

Freixa Z, 2000, APPL ORGANOMET CHEM, V14, P57, DOI 10.1002/(SICI)1099-0739(200001)14:1<57::AID-AOC960>3.3.CO

[6]

2-C

[7] Rhodium-catalyzed asymmetric arylation of imines with organostannanes. Asymmetric synthesis of diarylmethylamines [J].

Hayashi, T ;

Ishigedani, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (05) :976-977

[8] WATER-SOLUBLE METAL-COMPLEXES AND CATALYSTS .7. NEW EFFICIENT WATER-SOLUBLE CATALYSTS FOR 2-PHASE OLEFIN HYDROFORMYLATION - BINAS-NA, A SUPERLATIVE IN PROPENE HYDROFORMYLATION [J].

HERRMANN, WA ;

KOHLPAINTNER, CW ;

MANETSBERGER, RB ;

BAHRMANN, H ;

KOTTMANN, H .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 97 (02) :65-72

[9] Synthesis of the first water-soluble chiral tetrahydroxy diphosphine Rh(I) catalyst for enantioselective hydrogenation [J].

Holz, J ;

Heller, D ;

Stürmer, R ;

Börner, A .

TETRAHEDRON LETTERS, 1999, 40 (39) :7059-7062

[10] ENHANCEMENT OF OLEFIN HYDROFORMYLATION RELATED TO SUPPORTED BIMETALLIC RH-CO CLUSTERS [J].

HUANG, L ;

XU, YD ;

PIAO, GJ ;

LIU, AM ;

ZHANG, WT .

CATALYSIS LETTERS, 1994, 23 (1-2) :87-95