Solid-bound, proton-driven, fluorescent 'off-on-off' switches based on PET (photoinduced electron transfer)

被引：44

作者：

Brown, Gareth J. ^{[1
]}

de Silva, A. Prasanna ^{[1
]}

James, Mark R. ^{[2
]}

McKinney, Bernadine O. F. ^{[1
]}

Pears, David A. ^{[2
]}

Weir, Sheenagh M. ^{[1
]}

机构：

[1] Queens Univ Belfast, Sch Chem & Chem Engn, Belfast BT9 5AG, Antrim, North Ireland

[2] Avecia Ltd, Manchester M9 8ZS, Lancs, England

来源：

TETRAHEDRON | 2008年 / 64卷 / 36期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/j.tet.2008.04.103

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Anthracene-based, H(+)-driven, 'off-on-off' fluorescent PET (photoinduced electron transfer) switches. are immobilized on organic and inorganic polymeric solids in the form of Tentagel(R) and silica, respectively. The environment of the organic bead displaces apparent switching thresholds towards lower pH Values whereas the Si-O(-) groups of silica electrostatically cause the opposite effect. These switches are ternary logic gate tags, one of which can be particularly useful in Strengthening molecular computational identification (MCID) of small solid objects. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：8301 / 8306

页数：6

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