Solution-Shear-Processed Quaterrylene Diimide Thin-Film Transistors Prepared by Pressure-Assisted Thermal Cleavage of Swallow Tails

被引:62
作者
Oh, Joon Hak [2 ,3 ]
Lee, Wen-Ya [2 ,4 ]
Noe, Torsten [1 ]
Chen, Wen-Chang [4 ]
Koenemann, Martin [1 ]
Bao, Zhenan [2 ]
机构
[1] BASF SE, D-67056 Ludwigshafen, Germany
[2] Stanford Univ, Dept Chem Engn, Stanford, CA 94305 USA
[3] Ulsan Natl Inst Sci & Technol, Sch Nanobiosci & Chem Engn, Ulsan 689798, South Korea
[4] Natl Taiwan Univ, Dept Chem Engn, Taipei 10764, Taiwan
关键词
REMOVABLE SOLUBILIZING GROUPS; HIGH-PERFORMANCE; PENTACENE PRECURSOR; PERYLENE; DYES; DESIGN; SEMICONDUCTORS; DERIVATIVES; FLUORESCENT; TERRYLENE;
D O I
10.1021/ja110486s
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A scalable synthesis of swallow-tailed quaterrylene diimides (STQDIs) and a method for the solution processing of sparingly soluble quaterrylene diimide (QDI) thin films are described. The pressure-assisted thermal cleavage of swallow tails yields crystalline QDI layers with electron mobility up to 0.088 cm(2) V(-1) s(-1). The developed method opens up a new route toward the solution processing of higher rylene diimides with poor solubility.
引用
收藏
页码:4204 / 4207
页数:4
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