Diisopropylammonium oxalatotriphenylstannate

被引：20

作者：

Ng, SW ^{[1
]}

Hook, JM

机构：

[1] Univ Malaya, Inst Postgrad Studies & Res, Kuala Lumpur 50603, Malaysia

[2] Univ New S Wales, Sch Chem, NMR Facil, Sydney, NSW 2052, Australia

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270198011858

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coordination polyhedron of the five-coordinate Sn atom in the title compound, diisopropylammonium (oxalato-O-1, O-2)triphenylstannate, [NH2(C3H7)(2)][Sn-(C6H5)(3)(C2O3)], is a cis-C3SnO2 trigonal bipyramid [Sn-O-eq = 2.115(1) and Sn-O-ax = 2,260(1) Angstrom] that is approximately 50% displaced towards the square pyramid along the Berry pseudo-rotation pathway. Two cations and two anions participate in a hydrogen-bonded cluster [N .. O 2.808 (3)-3.044 (3) Angstrom].

引用

页码：310 / 312

页数：3

共 12 条

[1]

*ENR NON, 1988, CAD 4 VAX PC FORTR S

[2]

HARMS K, 1997, XCAD4 PROGRAM LP COR

[3]

Johnson C. K., 1976, ORNL5138

[4]

KRETSCHMAR M, 1994, CAD 4 C

[5] Diisopropylammonium (mercaptoacetato-S,O)triphenylstannate [J].

Ng, SW ;

Das, VGK ;

Yap, G ;

Rheingold, AL .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 :1369-1371

[6]

NG SW, 1993, J ORGANOMET CHEM, V456, P175

[7] STRUCTURAL STUDIES ON OXALATOTRIORGANOSTANNATES - CRYSTAL-STRUCTURE OF TRIMETHYLSULFONIUM CATENA-O, O'-OXALATOTRIPHENYLSTANNATE [J].

NG, SW ;

DAS, VGK ;

LUO, BS ;

MAK, TCW .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1994, 209 (11) :882-884

[8]

NG SW, 1995, MALAYS J SCI B, V16, P85

[9] A SEMI-EMPIRICAL METHOD OF ABSORPTION CORRECTION [J].

NORTH, ACT ;

PHILLIPS, DC ;

MATHEWS, FS .

ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :351-&

[10]

Sheldrick G.M., 1997, SHELXTL-97

← 1 2 →