A T-shaped platinum(II) boryl complex as the precursor to a platinum compound with a base-stabilized borylene ligand

被引:107
作者
Braunschweig, H [1 ]
Radacki, K [1 ]
Rais, D [1 ]
Scheschkewitz, D [1 ]
机构
[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany
关键词
boron; boryl ligands; borylene ligands; platinum; structure elucidation;
D O I
10.1002/anie.200501588
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Chemical Equation Presented) "T" time: A cationic, three-coordinate T-shaped platinum boryl complex (see structure) serves as the precursor to a cationic platinum complex featuring a base-stabilized borylene ligand. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:5651 / 5654
页数:4
相关论文
共 55 条
[41]  
2-H
[42]  
MITCHELL GP, 1998, J AM CHEM SOC, V120, P7365
[43]   CONTROL OF INTRAMOLECULAR BETA-HYDROGEN MIGRATION IN COORDINATIVELY UNSATURATED (DIPHOSPHINE)PLATINUM ETHYL CATIONS [J].
MOLE, L ;
SPENCER, JL ;
CARR, N ;
ORPEN, AG .
ORGANOMETALLICS, 1991, 10 (01) :49-52
[44]   The chemistry of borylstannanes: Oxidative addition to palladium species and its application to palladium-catalyzed borylstannation of alkynes [J].
Onozawa, S ;
Hatanaka, Y ;
Sakakura, T ;
Shimada, S ;
Tanaka, M .
ORGANOMETALLICS, 1996, 15 (26) :5450-5452
[45]   Crystal structure of Os(Bcat)Cl(CO)(PPh3)2 and the syntheses and structural studies of derived cationic and neutral osmium boryl complexes [J].
Rickard, CEF ;
Roper, WR ;
Williamson, A ;
Wright, LJ .
ORGANOMETALLICS, 1998, 17 (22) :4869-4874
[46]   Tethered boryl and base-stabilized borylene osmium complexes from the reaction of Os(BCl2)Cl(CO)(PPh3)2 with 2-aminopyridine [J].
Rickard, CEF ;
Roper, WR ;
Williamson, A ;
Wright, LJ .
ORGANOMETALLICS, 2002, 21 (22) :4862-4872
[47]   STRUCTURAL CONSEQUENCES OF BONDING IN TRANSITION-METAL CARBENE COMPLEXES [J].
SCHUBERT, U .
COORDINATION CHEMISTRY REVIEWS, 1984, 55 (03) :261-286
[48]   Measurement of the barrier to β-hydride elimination in β-agostic palladium-ethyl complex:: A model for the energetics of chain-walking in (α-diimine)PdR+ olefin polymerization catalysts [J].
Shultz, LH ;
Brookhart, M .
ORGANOMETALLICS, 2001, 20 (19) :3975-3982
[49]   Does back-bonding involve bonding orbitals in boryl complexes? A theoretical DFT study [J].
Sivignon, G ;
Fleurat-Lessard, P ;
Onno, JM ;
Volatron, F .
INORGANIC CHEMISTRY, 2002, 41 (25) :6656-6661
[50]   Synthesis of rhodium and iridium boryl complexes via oxidative addition of haloboranes [J].
Souza, FES ;
Nguyen, P ;
Marder, TB ;
Scott, AJ ;
Clegg, W .
INORGANICA CHIMICA ACTA, 2005, 358 (05) :1501-1509